A single chain magnet involving hexacyanoosmate.
نویسندگان
چکیده
The first single chain magnet (SCM) based on orbitally degenerate hexacyanoosmate(III) was prepared. The high values of energy barriers for the [Mn(acacen)Os(CN)6](2-) complex of 81 and 48.4 K are the result of interplay of three axes anisotropic coupling of [Os(CN)6](3-) with zero field splitted Mn(3+).
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 54 شماره
صفحات -
تاریخ انتشار 2014